| Electron Transfer dynamics and enhanced H2 production activity of Hydrangea-like BiOBr/Bi2S3-based Photocatalysts with Cu-complex As a Redox Mediator | |
|---|---|
| 學年 | 110 |
| 學期 | 1 |
| 出版（發表）日期 | 2021-11-01 |
| 作品名稱 | Electron Transfer dynamics and enhanced H2 production activity of Hydrangea-like BiOBr/Bi2S3-based Photocatalysts with Cu-complex As a Redox Mediator |
| 作品名稱（其他語言） | |
| 著者 | Chi-Jung Chang；Chieh-Lin Huang；Yuan-Hsiang Yu；Ming-Chun Teng；Chao-Lung Chiang；Yan-Gu Lin |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Applied Surface Science 576(A), p.151870 |
| 摘要 | A composite photocatalyst consisting of the BiOBr/Bi2S3 heterojunction and a Cu complex exhibited high H2 production activity through an efficient transport of charge by redox couple Cu(II)/Cu(I) of the complex. BiOBr was prepared by a microwave solvothermal method. Then, the BiOBr/Bi2S3 composite was prepared as a heterojunction photocatalyst by an ion-exchange process. The copper complex was then introduced as a co-catalyst or a redox mediator. The morphology, crystal properties, optical properties, surface chemistry, photocurrent response, and photocatalytic activity of these BiOBr/Bi2S3/copper complex composites were investigated. The formation of a BiOBr/Bi2S3 heterojunction and the introduction of Cu complex improved the performance of the photocatalysts. For the first time, operando X-ray absorption spectra were recorded in situ to unveil the local interaction at the reactant-photocatalyst interface toward the photocatalysis reaction of BiOBr/Bi2S3-Cu complex photocatalyst in the sacrificial agent solution (Na2S, Na2SO3). |
| 關鍵字 | |
| 語言 | en |
| ISSN | |
| 期刊性質 | 國外 |
| 收錄於 | SCI SSCI Scopus |
| 產學合作 | |
| 通訊作者 | Chi-Jung Chang, Yan-Gu Lin |
| 審稿制度 | 是 |
| 國別 | NLD |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/127740 ) |
| SDGS | 可負擔的潔淨能源,產業創新與基礎設施 |
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