Ligand‐promoted Cooperative Electrochemical Oxidation of Bio‐alcohol on Distorted Cobalt Hydroxides for Bio‐hydrogen Extraction
學年 109
學期 2
出版（發表）日期 2021-04-27
作品名稱 Ligand‐promoted Cooperative Electrochemical Oxidation of Bio‐alcohol on Distorted Cobalt Hydroxides for Bio‐hydrogen Extraction
作品名稱（其他語言）
著者 Chen Deng；Kuang-Hsu Wu；Xinxin Lu；Soshan Cheong；Richard Tilley；Chao-Lung Chiang；Yu-Chang Lin；Yan-Gu Lin；Wensheng Yan；Jason Scott；Rose Amal；Da-Wei Wang
單位
出版者
著錄名稱、卷期、頁數 ChemSusChem 14(12), p.2612-2620
摘要 Hydrogen is increasingly viewed as a game-changer in the clean energy sector. Renewable hydrogen production from water is industrialized by integrating water electrolysis and renewable electricity, but the current cost of water-born hydrogen remains high though. An ideal scenario would be to produce value-added chemicals along with hydrogen so the cost can be partially offset. Herein, facilitated bio-hydrogen extraction and biomass-derived chemical formation from sugar-derived 5-hydroxymethyfurfural (HMF) were achieved via the in-situ transformation of cobalt-bound electrocatalysts. The cyanide-bound cobalt hydroxide exhibited a low voltage at 1.55 V at 10 mA cm−2 for bio-hydrogen production, compared with an iridium catalyst (1.75 V). The interaction between the biomass intermediate and the cyanide ligand is suggested to be responsible for the improved activity.
關鍵字
語言 en_US
ISSN
期刊性質 國外
收錄於 SCI SSCI Scopus
產學合作
通訊作者 Kuang-Hsu Wu, Da-Wei Wang
審稿制度 是
國別 USA
公開徵稿
出版型式 ,電子版
相關連結

機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/127734 )

SDGS 負責任的消費與生產,夥伴關係,可負擔的潔淨能源,產業創新與基礎設施