End Group Modification of Polynorbornenes
學年 103
學期 1
出版(發表)日期 2014-12-01
作品名稱 End Group Modification of Polynorbornenes
著者 Lin, Ting-Wei; Chou, Chih-Ming; Lin, Nai-Ti; Lin, Cheng-Lan; Luh, Tien-Yau
單位 淡江大學化學工程與材料工程學系
出版者 Weinheim: Wiley - V C H Verlag GmbH & Co. KGaA
著錄名稱、卷期、頁數 Macromolecular Chemistry and Physics 215(23), pp.2357−2364
摘要 Polynorbornenes with allylic acetoxy terminus are obtained by ring-opening metathesis polymerization of the norbornene derivatives followed by quenching with 1,4-diacetoxy-2Z-butene. Treatment of these polymers with a range of nucleophiles in the presence of a Pd-catalyst gives the corresponding polynorbornenes bearing different end groups. The same protocol is used to modify the end groups of polymeric ladderphanes. Incorporation of an end-group-modified polynorbornene on indium tin oxide (ITO) surface perturbs the electrochemical properties of the ITO electrode.
關鍵字 end‐group modification;ladderphanes;palladium catalysts;polynorbornene;ring‐opening metathesis polymerization
語言 en
ISSN 1521-3935
期刊性質 國外
收錄於 SCI
通訊作者 Luh, Tien-Yau
國別 DEU
出版型式 ,電子版,紙本

機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/99715 )