| Magnetic Hyperfine Mössbauer Spectra of Ferrocenyaldimines-FeCl3 Adducts | |
|---|---|
| 學年 | 82 |
| 學期 | 1 |
| 出版（發表）日期 | 1993-08-01 |
| 作品名稱 | Magnetic Hyperfine Mössbauer Spectra of Ferrocenyaldimines-FeCl3 Adducts |
| 作品名稱（其他語言） | |
| 著者 | 李綺縑; Lee, C. J.; 魏和祥; Wei, Ho-hsiang |
| 單位 | 淡江大學化學學系 |
| 出版者 | 臺北市：中國化學學會 |
| 著錄名稱、卷期、頁數 | Journal of the Chinese Chemical Society=中國化學會會誌 40(4), pp.355-359 |
| 摘要 | Ferrocenylaldimines (Fc-CH=N-R) were prepared by condensation of Schiff base of formylferrocene with polyacenylamines RNH/sub 2/; R=naphthyl, anthracenyl and pyrenyl groups. This step was followed by oxidation with FeCl/sub 3/ to give [ Fc-CH=NR ] - FeCl/sub 3/ adducts. The electronic state of iron in these adducts was investigated by means of /sup 57/Fe Mossbauer spectra except for [ Fc-CH=N-Pyr ] -FeCl/sub 3/ showed that only a doublet was observed at ambient temperature. As the temperature was decreased below 200K, additional magnetic hyperfine splitting was observed characteristic of ferric oxide. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 0009-4536 |
| 期刊性質 | 國內 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25032 ) |
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