| Mössbauer and Electrochemical Studies of Bridged Biferrocenes and Biferrocenylenes | |
|---|---|
| 學年 | 72 |
| 學期 | 2 |
| 出版（發表）日期 | 1984-03-01 |
| 作品名稱 | Mössbauer and Electrochemical Studies of Bridged Biferrocenes and Biferrocenylenes |
| 作品名稱（其他語言） | |
| 著者 | 魏和祥; Wei, Ho-hsiang; 張信貞; Chang, S. J. |
| 單位 | 淡江大學化學學系 |
| 出版者 | 臺北市：中國化學學會 |
| 著錄名稱、卷期、頁數 | 中國化學會會誌=Journal of the Chinese Chemical Society 31(1)，頁9-14 |
| 摘要 | A series of neutral and oxidized π-bridged biferrocenes (Fc－x－Fc) and biferrocenylenes (FC(－x－)2Fc) (x=－CH=CH－, －CH3C=CCH3－) were prepared and their physical properties have been studied by means of Mossbauuer and cyclic voltammetry. The electrode reaction of these bridged ferrocene derivatives appears to involve a consecutive two-step oxidation process. The results also show that the voltage difference between the first and second oxidaton potentials of the bridged biferrocenes was found to be largely exceeded that founded for the corresponding the bridged biferrocenylenes. The Mossbauer date show that the oxidation of doubly bridged Fc(－x－)2Fc with iodine, DDQ, and TCNQ given the corresponding deoxidized salts only and stable mixed-valence compounds were found. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 0009-4536 |
| 期刊性質 | 國內 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25060 ) |
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