A two-dimensional CuIIGdIII compound self-assembled by H-bonding and intermolecular weak coordinate bonding between the dinuclear cores: structure and magnetic properties
學年 91
學期 1
出版（發表）日期 2002-08-01
作品名稱 A two-dimensional CuIIGdIII compound self-assembled by H-bonding and intermolecular weak coordinate bonding between the dinuclear cores: structure and magnetic properties
作品名稱（其他語言）
著者 魏和祥; Wei, Ho-hsiang; Mohanta, Sasankasekhar; Lin, Hsin-huang; Lee, Chin-jhan
單位 淡江大學化學學系
出版者 Elsevier
著錄名稱、卷期、頁數 Inorganic Chemistry Communications 5(8), pp.585-588
摘要 A heteronuclear CuIIGdIII complex [CuIILGdIII(NO3)3] with the hexadentate Shiff-base compartmental ligand N,N′-ethylenebis(3-ethoxysalicylaldiimine) (H2L) has been synthesized and structurally characterized. The intermolecular semicoordination of nitrate oxygen to copper(II) results a one-dimensional zigzag chain, which are linked by H-bonding to form a two-dimensional sheet. Magnetic studies reveal ferromagnetic interaction within the dinuclear core and antiferromagnetic interaction propagated through the extended network (Full-size image (<1 K), where H=−2JSCu·SGd+β(gCu·SCu+gGd·SGd)H−zJ′〈S4Z〉S4Z).
關鍵字 Two-dimensional; H-bonding; Magnetic properties; Gadolinium
語言 en
ISSN 1387-7003
期刊性質 國內
收錄於
產學合作
通訊作者
審稿制度 否
國別 TWN
公開徵稿
出版型式 ,電子版
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