New μ-oxo-bridged tetranuclear Cu(II) complex with Schiff-base ligand: Synthesis, crystal structure and magnetic properties | |
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學年 | 96 |
學期 | 1 |
出版(發表)日期 | 2007-10-01 |
作品名稱 | New μ-oxo-bridged tetranuclear Cu(II) complex with Schiff-base ligand: Synthesis, crystal structure and magnetic properties |
作品名稱(其他語言) | |
著者 | 魏和祥; Wei, Ho-hsiang; Lu, Jian-wei; Huang, Yao-hsuan; Lo, Shun-i |
單位 | 淡江大學化學學系 |
出版者 | Elsevier |
著錄名稱、卷期、頁數 | Inorganic Chemistry Communications 10(10), pp.1210-1213 |
摘要 | A new μ-oxo-bridged Cu(II) complex with cubane-like tetranuclear copper(II) complex, [Cu4(L1)4] · 4H2O (1) (H2L1 = 2-(3-methoxy-salicylidene-amino)-benzyl-alcohol), has been prepared, and structurally characterized by X-ray crystallography. Complex 1 crystallized in the monoclinic space group P21/n and has a tetranuclear core of Cu4O4. The temperature dependence of magnetic susceptibility measurements shown that complex 1 exhibits a strong antiferromagnetic interaction with J = −103.4 cm−1. |
關鍵字 | Copper(II) complexes;Copper(II) clusters;Crystal structure;Magnetic properties |
語言 | en |
ISSN | 1387-7003 |
期刊性質 | 國外 |
收錄於 | |
產學合作 | |
通訊作者 | |
審稿制度 | 否 |
國別 | NLD |
公開徵稿 | |
出版型式 | ,紙本 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25099 ) |