| Ferromagnetic Exchange in Two Dicopper(II) Complexes Using a μ-Alkoxo-μ-7-azaindolate Bridge | |
|---|---|
| 學年 | 92 |
| 學期 | 2 |
| 出版（發表）日期 | 2004-05-03 |
| 作品名稱 | Ferromagnetic Exchange in Two Dicopper(II) Complexes Using a μ-Alkoxo-μ-7-azaindolate Bridge |
| 作品名稱（其他語言） | |
| 著者 | Chou, Yi-chian; Huang, Shu-fei; Koner, Rajesh; Lee, Gene-hsiang ; Wang, Yu; Mohanta, Sasankasekhar; 魏和祥; Wei, Ho-hsiang |
| 單位 | 淡江大學化學學系 |
| 出版者 | American Chemical Society (ACS) |
| 著錄名稱、卷期、頁數 | Inorganic chemistry 43(9), pp.2759-2761 |
| 摘要 | Syntheses, structures, and magnetic properties of two heterobridged μ-alkoxo-μ-7-azaindolate dicopper(II) complexes, [CuII2(L−F)(μ-C7H5N2)] (1) and [CuII2(L−H)(μ-C7H5N2)]·CH3OH (2) (H3L−F = 1,3-bis(3-fluorosalicylideneamino)-2-propanol; H3L−H = 1,3-bis(salicylideneamino)-2-propanol) have been reported. Aside from being a new type of heterobridged complex, 1 and 2 exhibit ferromagnetic interaction (2J = 52 cm-1 for 1 and 33.4 cm-1 for 2) despite orbital complementarity (7-azaindolate HOMO is antisymmetric). |
| 關鍵字 | |
| 語言 | en |
| ISSN | 0020-1669 |
| 期刊性質 | 國內 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/24982 ) |
GoogleAnalytics