Direct 129 Xe-NMR spectroscopy evidence of a mesogenic dendrimer with free void space
學年 111
學期 2
出版（發表）日期 2023-02-28
作品名稱 Direct 129 Xe-NMR spectroscopy evidence of a mesogenic dendrimer with free void space
作品名稱（其他語言）
著者 Yao-Chih Lu, Roberto Anedda, Hsiu-Hui Chen, Hui-Chu Hsu, Shun-Ju Hsu, Christopher Ratcliffe, Long-Li Lai, John Ripmeester, Hsiu-Fu Hsu
單位
出版者
著錄名稱、卷期、頁數 Journal of Materials Chemistry C
摘要 A dendrimer with three-fold symmetry and piperazinoamido moieties was prepared in ∼35% yield. This molecule was observed to exhibit columnar phases on thermal treatment and have free void space in the mesogenic and solid states based on a 129Xe-NMR study. The piperazinoamido moiety was indicated in a theoretical calculation to cause the dendritic framework to become twisted between the central core and periphery—thus resulting in the dendrimer forming a free void space inside the framework after having self-assembled into columnar stacks.
關鍵字
語言 en
ISSN 2050-7534
期刊性質 國外
收錄於 SCI
產學合作
通訊作者
審稿制度 否
國別 GBR
公開徵稿
出版型式 ,電子版
相關連結

機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/125618 )