Li3B8O13X (X = Cl and Br): Two New Noncentrosymmetric Crystals with Large Birefringence Induced by BO3 Units
學年 111
學期 2
出版（發表）日期 2023-02-16
作品名稱 Li3B8O13X (X = Cl and Br): Two New Noncentrosymmetric Crystals with Large Birefringence Induced by BO3 Units
作品名稱（其他語言）
著者 Mei Hu, Nuerbiye Tuerhong, Zhaohui Chen, Qun Jing, Ming-Hsien Lee
單位
出版者
著錄名稱、卷期、頁數 Inorganic Chemistry 62(8), pp.3609−3615
摘要 Enthusiasm for the exploration of nonlinear alkali metal borates remains high. Focusing on the Li–B–O–X (X = Cl and Br) system, two examples of noncentrosymmetric borates, Li3B8O13Cl and Li3B8O13Br, were obtained using a high-temperature solution method under vacuum conditions. Structurally, the Li3B8O13X crystals exhibit two independent alternately arranged three-dimensional B–O network structures formed by the basic building block unit B8O16. The performance measurements demonstrate their short ultraviolet cutoff edges. The theoretical calculation indicates that the BO3 units dominate the contribution to their large optical anisotropy with the birefringence, 0.094 and 0.088@1064 nm for Li3B8O13Cl and Li3B8O13Br, respectively.
關鍵字
語言 en_US
ISSN 0020-1669; 1520-510X
期刊性質 國外
收錄於 SCI
產學合作
通訊作者
審稿制度 否
國別 USA
公開徵稿
出版型式 ,電子版
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機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/125523 )