學年
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112 |
學期
|
1 |
出版(發表)日期
|
2023-11-14 |
作品名稱
|
Palladium-catalyzed cascade endo-dig cycloisomerization and olefination with alkenes to access fused oxatricyclic compounds |
作品名稱(其他語言)
|
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著者
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Yi-En Liang Yi-En Liang National Research Institute of Chinese Medicine, Ministry of Health and Welfare, Taipei 112304, Taiwan, R.O.C. More by Yi-En Liang , Ming-Yiang Chang, Hsi Ho, Chun-Tang Chiou, Balaji D. Barve, and Wen-Tai Li* |
單位
|
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出版者
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著錄名稱、卷期、頁數
|
Organic Letters, 2023, 25, 46, 8194–8198. |
摘要
|
A novel cascade Pd(II)-catalyzed endo-dig cycloisomerization and olefination reaction of 2-benzyl-3-alkynyl chromones with activated/unactivated alkenes has been developed for the synthesis of fused oxatricyclic compounds. This concise one-pot synthetic approach was applied to the difunctionalization of unbiased alkynes based on 2-benzyl-3-(alkynyl)-4H-chromen-4-one via O-attack endo-dig cycloisomerization, followed by olefination with both activated and unactivated alkenes. |
關鍵字
|
Addition reactions,Catalysts,Cyclization,Hydrocarbons,Palladium |
語言
|
en_US |
ISSN
|
|
期刊性質
|
國外 |
收錄於
|
SCI
Scopus
|
產學合作
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通訊作者
|
Wen-Tai Li (李文泰) |
審稿制度
|
是 |
國別
|
USA |
公開徵稿
|
|
出版型式
|
,電子版,紙本 |