Palladium-catalyzed cascade endo-dig cycloisomerization and olefination with alkenes to access fused oxatricyclic compounds | |
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學年 | 112 |
學期 | 1 |
出版(發表)日期 | 2023-11-14 |
作品名稱 | Palladium-catalyzed cascade endo-dig cycloisomerization and olefination with alkenes to access fused oxatricyclic compounds |
作品名稱(其他語言) | |
著者 | Yi-En Liang Yi-En Liang National Research Institute of Chinese Medicine, Ministry of Health and Welfare, Taipei 112304, Taiwan, R.O.C. More by Yi-En Liang , Ming-Yiang Chang, Hsi Ho, Chun-Tang Chiou, Balaji D. Barve, and Wen-Tai Li* |
單位 | |
出版者 | |
著錄名稱、卷期、頁數 | Organic Letters, 2023, 25, 46, 8194–8198. |
摘要 | A novel cascade Pd(II)-catalyzed endo-dig cycloisomerization and olefination reaction of 2-benzyl-3-alkynyl chromones with activated/unactivated alkenes has been developed for the synthesis of fused oxatricyclic compounds. This concise one-pot synthetic approach was applied to the difunctionalization of unbiased alkynes based on 2-benzyl-3-(alkynyl)-4H-chromen-4-one via O-attack endo-dig cycloisomerization, followed by olefination with both activated and unactivated alkenes. |
關鍵字 | Addition reactions,Catalysts,Cyclization,Hydrocarbons,Palladium |
語言 | en_US |
ISSN | 1523-7060; 1523-7052 |
期刊性質 | 國外 |
收錄於 | SCI Scopus |
產學合作 | |
通訊作者 | Wen-Tai Li (李文泰) |
審稿制度 | 是 |
國別 | USA |
公開徵稿 | |
出版型式 | ,電子版,紙本 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/125564 ) |