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學年
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112 |
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學期
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2 |
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出版（發表）日期
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2024-06-08 |
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作品名稱
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Facile synthesis of homoallylamines via α-regioselectivity in ultrasonic mediation and γ-adduct syn-stereoselective allylation with AlCl3-catalysis |
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作品名稱（其他語言）
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著者
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Lee, Chuo-yu; Yen, Ya-chuan; Lee, Shih-yuan |
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單位
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出版者
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著錄名稱、卷期、頁數
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Tetrahedron Letters 114, 155134 |
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摘要
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The allylation reaction of aldimines with allyl metal reagents is an important synthetic method for the preparation of homoallylamines. Therefore, we wish to report a highly regioselective and stereoselective allylation reaction under sonochemical Barbier-type reaction conditions. The high yields of regioselective α-adducts were achieved by reacting cinnamyl bromide, zinc, 1,2-dibromoethane, and aldimine in THF under sonochemical Barbier-type conditions. Highly regioselective and stereoselective allylation reactions were also achieved under Lewis acid-promoted Barbier-type reaction conditions. |
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關鍵字
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Homoallylamine;Sonochemical Barbier-type reaction;Lewis acid |
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語言
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en_US |
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ISSN
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1873-3581 |
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期刊性質
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國外 |
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收錄於
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SCI
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產學合作
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通訊作者
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Adam Shih-Yuan |
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審稿制度
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否 |
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國別
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TWN |
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公開徵稿
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出版型式
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,電子版 |
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