Characteristics and photocatalytic kinetics of ZnO films on glass tubes
學年 111
學期 1
出版(發表)日期 2022-09-01
作品名稱 Characteristics and photocatalytic kinetics of ZnO films on glass tubes
作品名稱(其他語言)
著者 Hsuan-Fu Yu ; I-Ching Pei
單位
出版者
著錄名稱、卷期、頁數 Physica B 640
摘要 ZnO films on glass tubes were prepared by chemical bath deposition method. The glass tubes were surface-activated by KMnO4(aq) and then submerged in an alkaline aqueous solution, containing Zn(CH3COO)2, NH4OH and HO(CH2)2NH2 at 75 oC to undergo film formation. The microstructures of the dried and calcined ZnO films prepared using different conditions were examined. The films formed on KMnO4-activated glass tubes are composed of steeple-typed wurtzite ZnO columns. Photocatalytic activities of the ZnO films were evaluated by photocatalytically degrading the methylene blue (MB) in water under UV-light irradiation. The apparent reaction order for MB photocatalytic degradation by the ZnO films was 1st-order and the reaction rate constants (k), based on the area of substrates coated by the film, were estimated. The ZnO films prepared using a volume ratio of ammonia/ethanolamine = 2/12 and calcined at 500 oC gave a photocatalytic performance with an average k = 0.5490.021 L/(m2·min).
關鍵字 ZnO films; Photocatalysis; Chemical bath deposition; Dye degradation; Kinetics
語言 en_US
ISSN 0921-4526
期刊性質 國外
收錄於 SCI EI
產學合作
通訊作者 Hsuan-Fu Yu
審稿制度
國別 NLD
公開徵稿
出版型式 ,電子版,紙本