教師資料查詢 | 類別: 期刊論文 | 教師: 李明憲LEE, MING-HSIEN (瀏覽個人網頁)

標題:K8Cd21Pb7(P2O7)16 and KCd2P3O10: Two new phosphates featuring special structure configurations
學年109
學期2
出版(發表)日期2021/02/01
作品名稱K8Cd21Pb7(P2O7)16 and KCd2P3O10: Two new phosphates featuring special structure configurations
作品名稱(其他語言)
著者Na Li; Lu Qi; Lu Li; Zhongqi Jiang; Jihong Fu; Ming-Hsien Lee; Zhaohui Chen
單位
出版者
著錄名稱、卷期、頁數Journal of Solid State Chemistry v.294, 121834
摘要Two new phosphates, KCd2P3O10 and K8Cd21Pb7(P2O7)16, have been obtained using high-temperature molten method for the first time. They show three-dimensional (3D) framework structures composed of [Cd2P3O18]∞ layers for KCd2P3O10 and [Cd36P48O237]∞ corrugated layers for K8Cd21Pb7(P2O7)16. To the best of our knowledge, K8Cd21Pb7(P2O7)16 is the first Cd-based phosphate that is constructed by tremendous [Cd18P24O121]∞ anionic duplicate units, which contain intriguing multimember-rings (6-MR, 8-MR, 16-MR). In addition, K8Cd21Pb7(P2O7)16 contains coexistent Cd2O10 single rings and Cd3O12 twin rings, which have not been found in other Cd-based phosphates. The comparison of structures was carried out among all the relevant anhydrous Cd-based phosphates. Combining with theoretical analysis, the relationship between electronic structures and optical properties is further elaborated.
關鍵字KCd2P3O10;K8Cd21Pb7(P2O7)16;[Cd18P24O121] skeleton;Structural comparison;Theoretical calculation
語言英文
ISSN
期刊性質國外
收錄於SCI;
產學合作
通訊作者
審稿制度
國別英國
公開徵稿
出版型式,電子版,紙本
相關連結
SDGs
Google+ 推薦功能,讓全世界都能看到您的推薦!