Enhancing photocatalytic ability of TiO2 films using gel-derived P/Si-TiO2powder | |
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學年 | 109 |
學期 | 1 |
出版(發表)日期 | 2021-01-16 |
作品名稱 | Enhancing photocatalytic ability of TiO2 films using gel-derived P/Si-TiO2powder |
作品名稱(其他語言) | |
著者 | Yu, Hsuan-fu; Cheng, Chao-wei |
單位 | |
出版者 | |
著錄名稱、卷期、頁數 | Journal of Sol-Gel Science and Technology 97, p.259-270 |
摘要 | P/Si-TiO2 photocatalytic thick films on FTO glass substrates were prepared. TiO2 thin films, as base layer, were first coated on substrates using a spin-coating technique. The slurry containing P/Si-TiO2 nanoparticles was bar-coated on the surface of TiO2 base layer, followed by calcining at 550 °C. The resultant films were characterized using x-ray diffractometer, scanning electron microscope, UV–Vis spectrophotometer, crosscut adhesion test, and recycling-use test. Under 365-nm UV-light irradiation, abilities of the films to photocatalytically degrade methylene blue were evaluated. The apparent rate laws obeyed 1st-order and the corresponding reaction rate constants (k′), based on the coated area of substrates, were estimated. k′ of the thick film (thickness: 6.5 μm; composition: P/Si-TiO2 anatase crystallites with 16 nm average size) was 49.0 L/(m2-sub. h), which was about eight times of that of the thin film (k′ = 6.2 L/(m2-sub. h); thickness: 215 nm; composition: pure TiO2 anatase crystallites with 8-nm average size). |
關鍵字 | TiO2 films;Photocatalysis;Kinetics;Dye degradation;Optical properties;Microstructure |
語言 | en_US |
ISSN | 1573-4846 |
期刊性質 | 國外 |
收錄於 | SCI EI |
產學合作 | |
通訊作者 | |
審稿制度 | 是 |
國別 | USA |
公開徵稿 | |
出版型式 | ,電子版,紙本 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/120956 ) |