Microwave Assisted Synthesis of Dihydropyrrole by AgOAc Catalyzed Intramolecular Cyclization Reaction of Homopropargyl amine
學年 105
學期 2
出版(發表)日期 2017-06-01
作品名稱 Microwave Assisted Synthesis of Dihydropyrrole by AgOAc Catalyzed Intramolecular Cyclization Reaction of Homopropargyl amine
作品名稱(其他語言)
著者 Adam Shih-Yuan Lee; Szu-Huio Ma Lee; Yu-Ting Chang
單位
出版者
著錄名稱、卷期、頁數 Research on Chemical Intermediates 43(6), p.3493–3503
摘要 A series of 5-aryl dihydropyrrole was synthesized from the intramolecular cyclization reaction of homopropargyl amine in the presence of AgOAc as catalyst under microwave irradiation reaction conditions. The homopropargyl amine was prepared by the reaction of propargyl bromide with N-tosyl aldimine under a sonochemical Barbier-type reaction condition. Further aromatization reaction of 5-aryl dihydropyrrole in KOtBu/DMSO can afford 2-aryl pyrrole under microwave irradiation reaction conditions.
關鍵字 Homopropargyl amine;Dihydropyrrole;2-Aryl pyrrole;Sonochemical Barbier-type reaction;Microwave irradiation
語言 en_US
ISSN 0922-6168
期刊性質 國外
收錄於 SCI
產學合作
通訊作者 Adam Shih-Yuan Lee
審稿制度
國別 TWN
公開徵稿
出版型式 ,電子版
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機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/111951 )

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