Ionic Current Rectification in a pH-tunable Polyelectrolyte Brushes Functionalized Conical Nanopore: Effect of Salt Gradient
學年 104
學期 1
出版(發表)日期 2016-01-19
作品名稱 Ionic Current Rectification in a pH-tunable Polyelectrolyte Brushes Functionalized Conical Nanopore: Effect of Salt Gradient
作品名稱(其他語言)
著者 Lin, J.Y.; C.Y. Lin; J.P. Hsu; S. Tseng
單位
出版者
著錄名稱、卷期、頁數 Analytical Chemistry 88(2), p.1176-1187
摘要 The behavior of ionic current rectification (ICR) in a conical nanopore with its surface modified by pH-tunable polyelectrolyte (PE) brushes connecting two large reservoirs subject to an applied electric field and a salt gradient is investigated. Parameters including the solution pH, types of ionic species, strength of applied salt gradient, and applied potential bias are examined for their influences on the ionic current and rectification factor, and the mechanisms involved are investigated comprehensively. The ICR behavior depends highly on the charged conditions of the PE layer, the level of pH, the geometry of nanopore, and the thickness of the double layer. In particular, the distribution of ionic species and the local electric field near the nanopore openings play a key role, yielding profound and interesting results that are informative to device design as well as experimental data interpretation.
關鍵字
語言 en_US
ISSN 1520-6882
期刊性質 國外
收錄於 SCI EI
產學合作
通訊作者
審稿制度
國別 USA
公開徵稿
出版型式 ,電子版,紙本
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機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/119844 )