A Zirconium Macrocyclic Metal–Organic Framework with Predesigned Shape-Persistent Apertures
學年 105
學期 1
出版（發表）日期 2017-01-05
作品名稱 A Zirconium Macrocyclic Metal–Organic Framework with Predesigned Shape-Persistent Apertures
作品名稱（其他語言）
著者 Teng-Hao Chen; Ilya Popov; Ognjen S. Miljanic
單位
出版者
著錄名稱、卷期、頁數 Chemistry - A European Journal 23(2), pp.286-290
摘要 A microporous metal–organic framework (MOF) was synthesized from [Zr6O4(OH)4(C6H5COO)12] clusters and a triacid ligand based on a shape-persistent arylene ethynylene macrocycle. This framework, dubbed Zr-MCMOF, is held together by metal–ligand coordination and multiple weak interactions: hydrogen bonding, [π⋅⋅⋅π] stacking, and [C−H⋅⋅⋅π] interactions. The rigid ligand has a 9 Å-wide central void, which serves as a predesigned aperture for the 1D channels; all of the porosity of Zr-MCMOF comes from the ligand. The resulting framework possesses high hydrolytic and thermal stability and a flexible structure unique among Zr-based MOFs.
關鍵字 1D channels;macrocycles;metal–organic frameworks;shape persistency;zirconium
語言 en
ISSN 1521-3765
期刊性質 國外
收錄於 SCI
產學合作 國外
通訊作者 Teng-Hao Chen; Ognjen S. Miljanic
審稿制度 是
國別 DEU
公開徵稿
出版型式 ,電子版
相關連結

機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/109452 )