A Zirconium Macrocyclic Metal–Organic Framework with Predesigned Shape-Persistent Apertures | |
---|---|
學年 | 105 |
學期 | 1 |
出版(發表)日期 | 2017-01-05 |
作品名稱 | A Zirconium Macrocyclic Metal–Organic Framework with Predesigned Shape-Persistent Apertures |
作品名稱(其他語言) | |
著者 | Teng-Hao Chen; Ilya Popov; Ognjen S. Miljanic |
單位 | |
出版者 | |
著錄名稱、卷期、頁數 | Chemistry - A European Journal 23(2), pp.286-290 |
摘要 | A microporous metal–organic framework (MOF) was synthesized from [Zr6O4(OH)4(C6H5COO)12] clusters and a triacid ligand based on a shape-persistent arylene ethynylene macrocycle. This framework, dubbed Zr-MCMOF, is held together by metal–ligand coordination and multiple weak interactions: hydrogen bonding, [π⋅⋅⋅π] stacking, and [C−H⋅⋅⋅π] interactions. The rigid ligand has a 9 Å-wide central void, which serves as a predesigned aperture for the 1D channels; all of the porosity of Zr-MCMOF comes from the ligand. The resulting framework possesses high hydrolytic and thermal stability and a flexible structure unique among Zr-based MOFs. |
關鍵字 | 1D channels;macrocycles;metal–organic frameworks;shape persistency;zirconium |
語言 | en |
ISSN | 1521-3765 |
期刊性質 | 國外 |
收錄於 | SCI |
產學合作 | 國外 |
通訊作者 | Teng-Hao Chen; Ognjen S. Miljanic |
審稿制度 | 是 |
國別 | DEU |
公開徵稿 | |
出版型式 | ,電子版 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/109452 ) |