Trends in reactivity of electrodeposited 3d transition metals on gold revealed by operando soft x-ray absorption spectroscopy during water splitting
學年 105
學期 1
出版（發表）日期 2016-12-02
作品名稱 Trends in reactivity of electrodeposited 3d transition metals on gold revealed by operando soft x-ray absorption spectroscopy during water splitting
作品名稱（其他語言）
著者 J J Velasco-Vélez; Travis E Jones; Verena Pfeifer; Chung-Li Dong; Yu-Xun Chen; Chieh-Ming Chen; Hsin-Yu Chen; Ying-Rui Lu; Jin-Ming Chen; R Schlögl; A Knop-Gericke; C-H Chuang
單位
出版者
著錄名稱、卷期、頁數 Journal of Physics D: Applied Physics 50 (2), p.024002(10 pages)
摘要 We activated gold electrodes for their use as electrocatalyst for water splitting by electrodepositing Cu, Ni and Co. A combination of operando x-ray absorption spectroscopy and potentiometric control under aqueous conditions revealed the trends in reactivity yielded by these electrodes, which are directly associated with the cross- and overpotentials as well as the occupancy of the 3d orbitals. It was found that under anodic polarization the materials electrodeposited on gold suffer from a lack of stability, while under cathodic polarization they exhibit stable behavior. The observed activity is strongly related to the lack of stability shown by these composites under anodic polarization revealing a dynamic process ruled by corrosion. By operando x-ray absorption, we established that the overall enhancement of the activity for the oxygen evolution reaction is directly attributable to the cross-potential and corrosion process of the electrodeposited materials. It is associated with the high potential deposition, which is the origin of the incipient oxidation-corrosion resistance of the lattice. We conclude that the observed trends in the total current are directly associated with the loss of oxygen in the metal-oxide lattice and the subsequent dissolution of metallic ions in the electrolyte under anodic polarization.
關鍵字 operando soft x-ray absorption;trends in activity/stability;3d transition metals;water splitting
語言 en
ISSN 1361-6463
期刊性質 國外
收錄於 SCI
產學合作
通訊作者 J J Velasco-Vélez;Cheng-Hao Chuang
審稿制度 是
國別 GBR
公開徵稿
出版型式 ,電子版
相關連結

機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/109220 )