Hydride-Induced Anionic Cyclization: An Efficient Method for the Synthesis of 6-H-Phenanthridines via a Transition-Metal-Free Process
學年 103
學期 2
出版（發表）日期 2015-03-12
作品名稱 Hydride-Induced Anionic Cyclization: An Efficient Method for the Synthesis of 6-H-Phenanthridines via a Transition-Metal-Free Process
作品名稱（其他語言）
著者 謝仁傑
單位
出版者 ACS
著錄名稱、卷期、頁數 Organic Letters 17(6), p.1613-1616
摘要 A novel procedure for hydride-induced anionic cyclization has been developed. It includes the reduction of a biaryl bromo-nitrile with a nucleophilic aromatic substitution (SNAr). A range of polysubstituted 6-H-phenanthridines were so obtained in moderate to good yield with good substrate tolerance. This method involves a concise transition-metal-free process and was applied to synthesize natural alkaloids.
關鍵字
語言 en_US
ISSN 1523-7060
期刊性質 國外
收錄於 SCI
產學合作
通訊作者 謝仁傑
審稿制度 否
國別 USA
公開徵稿
出版型式 ,電子版
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