Ionic current in a pH-regulated nanochannel filled with multiple ionic species
學年 103
學期 1
出版(發表)日期 2014-11-01
作品名稱 Ionic current in a pH-regulated nanochannel filled with multiple ionic species
作品名稱(其他語言)
著者 Tseng, Shiojenn; Tai, Yi-Hsuan; Hsu, Jyh-Ping
單位 淡江大學數學學系
出版者 Heidelberg: Springer
著錄名稱、卷期、頁數 Microfluidics and Nanofluidics 17(5), pp.933-941
摘要 Considering recent widespread applications in nanofluidics, we analyze the ionic current in a pH-regulated nanochannel, using an aqueous NaCl solution in an SiO2 nanochannel with pH adjusted by HCl and NaOH as an example. The model assumed is closer to reality than that in previous analyses, where the channel surface is maintained either at constant potential or constant charge, and only ionic species coming from background salt are considered. The electrical potential, velocity distribution, and ionic current under various conditions are examined by varying the pH, the density of surface functional groups, and the background salt concentration. We show that neglecting ionic species other than those from back ground salt might yield appreciable deviation in ionic current. The mechanisms involved in ionic transport are discussed, and we show that the effects of double-layer thickness and surface potential yield complicated and interesting behaviors in ionic current.
關鍵字
語言 en
ISSN 1613-4982
期刊性質 國外
收錄於 SCI
產學合作
通訊作者 Hsu, Jyh-Ping
審稿制度
國別 DEU
公開徵稿
出版型式 ,紙本
相關連結

機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/102863 )

機構典藏連結