| Effects of Cooling Temperature and Aging Treatment on the Morphology of Nano- and Micro-porous EVOH Membranes by Thermal Induced Phase Separation Method | |
|---|---|
| 學年 | 102 |
| 學期 | 1 |
| 出版（發表）日期 | 2014-01-23 |
| 作品名稱 | Effects of Cooling Temperature and Aging Treatment on the Morphology of Nano- and Micro-porous EVOH Membranes by Thermal Induced Phase Separation Method |
| 作品名稱（其他語言） | |
| 著者 | Lin, Dar-jong; Cheng, Liao-ping |
| 單位 | 淡江大學化學工程與材料工程學系 |
| 出版者 | Hoboken: John Wiley & Sons, Inc. |
| 著錄名稱、卷期、頁數 | Journal of Applied Polymer Science 131(12), 40374 |
| 摘要 | Poly(ethylene-co-vinyl alcohol) (EVOH 32) / 1,3-propanediol mixtures are processed by thermally induced phase separation for the formation of porous membranes. The crystallization line was determined both by the cloud-point and DSC methods. Two precursor solution compositions, four quench temperatures and various aging times were explored. It is found possible to generate both polymer-crystallization controlled morphologies (for high quenches and/or sufficiently aged dopes), especially globular microporous ones, and novel nano-scale porous morphologies dominated by intra-binodal phase separation (for low quenches and limited or no precursor solution aging). Structural characterization of the membranes was accomplished via application of scanning electron microscopy and wide angle X-ray diffraction. |
| 關鍵字 | membranes;crystallization;ageing;nanostructured polymers;morphology |
| 語言 | en |
| ISSN | 1097-4628 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | Cheng, Liao-Ping |
| 審稿制度 | 是 |
| 國別 | USA |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/100127 ) |
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