| Electrophoresis of pH-regulated, zwitterionic particles: Effect of self-induced nonuniform surface charge | |
|---|---|
| 學年 | 102 |
| 學期 | 2 |
| 出版（發表）日期 | 2014-05-01 |
| 作品名稱 | Electrophoresis of pH-regulated, zwitterionic particles: Effect of self-induced nonuniform surface charge |
| 作品名稱（其他語言） | |
| 著者 | Chen, Yu-Yen; Hsu, Jyh-Ping; Tseng, Shiojenn |
| 單位 | 淡江大學數學學系 |
| 出版者 | Maryland Heights: Academic Press |
| 著錄名稱、卷期、頁數 | Journal of Colloid and Interface Science 421, pp.154-159 |
| 摘要 | The electrophoresis of a pH-regulated, zwittterionic nanoparticle, taking account of its self-induced nonuniform surface charge, the presence of multiple ionic species, and the effect of double-layer polarization, is modeled. This extends previous models to a case closer to reality because the charged properties of a particle can be influenced by both its physicochemical nature and the solution conditions. We show that the nonuniform surface charge distribution induces a local electric field having the direction either opposite to or the same as that of the applied electric field, thereby either reducing or raising the particle velocity. This effect is most important when both the surface potential and the degree of nonuniformality are high. The competition of the effects of the position dependent double layer thickness, the surface proton distribution, and the double-layer polarization yields complicated and interesting behaviors. Depending upon the level of pH, the influence of the types of background salt on the particle mobility can be significant. |
| 關鍵字 | Electrophoresis; pH-regulated nanoparticles; Self-induced nonuniform surface charge; Types of background electrolytes |
| 語言 | en |
| ISSN | 0021-9797 1095-7103 |
| 期刊性質 | 國外 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 是 |
| 國別 | USA |
| 公開徵稿 | |
| 出版型式 | 紙本 電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97854 ) |
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