| Rich man's proton: Triphenylphosphinegold as probe of hydride positions in organo- and bioorgano-metallic complexes | |
|---|---|
| 學年 | 101 |
| 學期 | 1 |
| 發表日期 | 2012-08-19 |
| 作品名稱 | Rich man's proton: Triphenylphosphinegold as probe of hydride positions in organo- and bioorgano-metallic complexes |
| 作品名稱（其他語言） | |
| 著者 | Darensbourg, Marcetta Y.; Hsieh, Chung-Hung; Brothers, Scott; Hall, Michael B. |
| 作品所屬單位 | 淡江大學化學學系 |
| 出版者 | |
| 會議名稱 | 244th ACS National Meeting & Exposition |
| 會議地點 | Philadelphia, PA, United States |
| 摘要 | The isolobal analogy that creates a surprising link between H and Ph3PAu has been used to prep. Ph3PAu "synthetic analogs" of transition metal hydrides to support expected, but crystallog. unconfirmed, hydride positions. The asym. structure of the diiron hydrogenase enzyme active site, [FeFe]-H2ase eas, suggests a terminal (rather than bridging) hydride position is a requirement for catalytic activity. Such asymmetry is also found in the all-carbonyl complexes HtFe(CO)4M(CO)5 -, M = Cr, Mo, W, for which (Ph3 |
| 關鍵字 | |
| 語言 | en |
| 收錄於 | |
| 會議性質 | 國際 |
| 校內研討會地點 | |
| 研討會時間 | 20120819~20120823 |
| 通訊作者 | |
| 國別 | USA |
| 公開徵稿 | Y |
| 出版型式 | 紙本 |
| 出處 | 244th ACS National Meeting & Exposition, INOR-261 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97604 ) |
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