| Critical precursors to biomimetics of the diiron hydrogenase enzyme active site: Carbon monoxide mobilized 2Fe2S carbonyl clusters | |
|---|---|
| 學年 | 101 |
| 學期 | 1 |
| 發表日期 | 2012-08-19 |
| 作品名稱 | Critical precursors to biomimetics of the diiron hydrogenase enzyme active site: Carbon monoxide mobilized 2Fe2S carbonyl clusters |
| 作品名稱（其他語言） | |
| 著者 | Darensbourg, Marcetta Y.; Crouthers, Danielle; Bethel, Ryan; Hsieh, Chung-Hung; Brothers, Scott M.; Hall, Michael B. |
| 作品所屬單位 | 淡江大學化學學系 |
| 出版者 | |
| 會議名稱 | 244th ACS National Meeting & Exposition |
| 會議地點 | Philadelphia, PA, United States |
| 摘要 | The impressive synthetic chem. that has developed following the elucidation of the organodiiron units within the [FeFe]-H2ase enzyme active site has largely depended on the availability of an easily accessed precursor, (μ2-S2)[Fe(CO)3]2. In reduced bis sulfide form, (μ2-S)2[Fe(CO)3]2 2-, alkylation and condensation at sulfur gives a well known range of products, advancing in the last decade to the more faithful analogs of the [FeFe]-H2ase eas, (μ2-SCH2 |
| 關鍵字 | |
| 語言 | en |
| 收錄於 | |
| 會議性質 | 國際 |
| 校內研討會地點 | |
| 研討會時間 | 20120819~20120823 |
| 通訊作者 | |
| 國別 | USA |
| 公開徵稿 | Y |
| 出版型式 | 紙本 |
| 出處 | 244th ACS National Meeting & Exposition, INOR-235 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97600 ) |
GoogleAnalytics