| Structural and spectroscopic features of mixed valent FeIIFeI complexes and factors related to the rotated configuration of diiron hydrogenase | |
|---|---|
| 學年 | 101 |
| 學期 | 2 |
| 發表日期 | 2013-04-07 |
| 作品名稱 | Structural and spectroscopic features of mixed valent FeIIFeI complexes and factors related to the rotated configuration of diiron hydrogenase |
| 作品名稱（其他語言） | |
| 著者 | Hsieh, Chung-Hung; Erdem, Ozlen; Harman, Scott; Singleton, Michael; Reijerse, Edward; Lubitz, Wolfgang; Popescu, Codrina; Reibenspies, Jospeh; Brothers, Scott; Hall, Michael; et a |
| 作品所屬單位 | 淡江大學化學學系 |
| 出版者 | |
| 會議名稱 | 245th ACS National Meeting & Exposition |
| 會議地點 | New Orleans, LA, United States |
| 摘要 | The compds. of this study served as structural and functional biomimetics of the [FeFe]-Hydrogenase active site and have demonstrated a redox level-dependent structural rearrangement that is unique in dinuclear organometallic chem. The distinctive "rotated", as contrasted to sym. butterfly, structure is the epicenter of the natural, base metal, hydrogen-producing catalysts. The installation of bridgehead bulk in the -SCH2CR2CH2S- dithiolate (R = Me, Et) model complexes produces 6-membered FeS2C3 cyclohexane-type rings that in the boat c... |
| 關鍵字 | |
| 語言 | en |
| 收錄於 | |
| 會議性質 | 國際 |
| 校內研討會地點 | |
| 研討會時間 | 20130407~20130411 |
| 通訊作者 | |
| 國別 | USA |
| 公開徵稿 | Y |
| 出版型式 | 紙本 |
| 出處 | 245th ACS National Meeting & Exposition, INOR-285 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97598 ) |
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