| Iron-nitrosyl paradigm for base metal proton reduction electrocatalysis | |
|---|---|
| 學年 | 102 |
| 學期 | 1 |
| 發表日期 | 2013-11-16 |
| 作品名稱 | Iron-nitrosyl paradigm for base metal proton reduction electrocatalysis |
| 作品名稱（其他語言） | |
| 著者 | Darensbourg, Marcetta Y.; Hsieh, Chung-hung; Erdem, Ozlen; Ding, Shengda; Crouthers, Danielle; Lubitz, Wolfgang; Popescu, Codrina; Reibenspies, Joseph; Hall, Michael B. |
| 作品所屬單位 | 淡江大學化學學系 |
| 出版者 | |
| 會議名稱 | 69th Southwest Regional Meeting of the American Chemical Society |
| 會議地點 | Waco, TX, United States |
| 摘要 | Base metal, mol. catalysts for the fundamental process of conversion of protons and electrons to dihydrogen remain a substantial synthetic goal related to a sustainable energy future. A novel approach has produced a diiron complex with bridging thiolates in the butterfly shape of the 2Fe2S core of the [FeFe]-hydrogenase active site, but with NO rather than CO or CN- ligands, that is demonstrated to maintain structural integrity in two redox levels. Various spectroscopies corroborate the roles of the iron centers in electrocatalytic proton redn. The binuclear [(NO)Fe(N2 |
| 關鍵字 | |
| 語言 | en |
| 收錄於 | |
| 會議性質 | 國際 |
| 校內研討會地點 | |
| 研討會時間 | 20131116~20131119 |
| 通訊作者 | |
| 國別 | USA |
| 公開徵稿 | Y |
| 出版型式 | 紙本 |
| 出處 | 69th Southwest Regional Meeting of the American Chemical Society, SWRM-576 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97595 ) |
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