| Electronic effects of metallodithiolate ligands on [FeFe]-H2ase active site model compounds | |
|---|---|
| 學年 | 101 |
| 學期 | 2 |
| 發表日期 | 2013-04-07 |
| 作品名稱 | Electronic effects of metallodithiolate ligands on [FeFe]-H2ase active site model compounds |
| 作品名稱（其他語言） | |
| 著者 | Ghosh, Pokhraj; Hsieh, Chung-Hung; Darensbourg, Marcetta Y. |
| 作品所屬單位 | 淡江大學化學學系 |
| 出版者 | |
| 會議名稱 | 245th ACS National Meeting & Exposition |
| 會議地點 | New Orleans, LA, United States |
| 摘要 | The reversible redn. of protons to form hydrogen gas is known to be catalyzed by the active-site of the diiron hydrogenase, [FeFe]-H2ase. The N2S2Ni (square planar), N2S2-Co(NO) and -Fe(NO) (square pyramidal) compds. are particularly interesting as the cis-dithiolates are noted for their nucleophilicity toward a diverse variety of electrophiles and their ability to lower the redn. potentials on coordination with M(CO)x. In this project a series of [FeFe]-H2ase active site model compds. are shown to form stable addu... |
| 關鍵字 | |
| 語言 | en |
| 收錄於 | |
| 會議性質 | 國際 |
| 校內研討會地點 | |
| 研討會時間 | 20130407~20130411 |
| 通訊作者 | |
| 國別 | USA |
| 公開徵稿 | Y |
| 出版型式 | 紙本 |
| 出處 | 245th ACS National Meeting & Exposition, INOR-281 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97594 ) |
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