| Cis-NiN2S2 metallodithiolates as mono- and bidentate S-donors to gold (I) | |
|---|---|
| 學年 | 101 |
| 學期 | 2 |
| 發表日期 | 2013-04-07 |
| 作品名稱 | Cis-NiN2S2 metallodithiolates as mono- and bidentate S-donors to gold (I) |
| 作品名稱（其他語言） | |
| 著者 | Pinder, Tiffany A.; Montalvo, Steven K.; Lunsford, Allen M.; Hsieh, Chung-Hung; Reibenspies, Joseph H.; Darensbourg, Marcetta Y. |
| 作品所屬單位 | 淡江大學化學學系 |
| 出版者 | |
| 會議名稱 | 245th ACS National Meeting & Exposition |
| 會議地點 | New Orleans, LA, United States |
| 摘要 | Metal-bound thiolates show S-based reactivity including alkylation, oxygenation, and metalation. We have studied the donating ability of a series of square planar,NiN2S2 complexes by reporter units such as tungsten carbonyls and dinitrosyl iron complexes. In this way nickel cis-dithiolates may be described as metallo ligands, comparable to diphenylphosphinoethane or bipyridine. Herein we describe the products of reaction of [NiN2S2 ]n (n = 0 or 2-) complexes with Ph3PAuCl, with expectation of a thiolate S-donor to... |
| 關鍵字 | |
| 語言 | en |
| 收錄於 | |
| 會議性質 | 國際 |
| 校內研討會地點 | |
| 研討會時間 | 20130407~20130411 |
| 通訊作者 | |
| 國別 | USA |
| 公開徵稿 | Y |
| 出版型式 | 紙本 |
| 出處 | 245th ACS National Meeting & Exposition, INOR-1363 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97592 ) |
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