Ambidentate thiocyanate ligand in dinitrosyl iron complexes
學年 101
學期 2
發表日期 2013-04-07
作品名稱 Ambidentate thiocyanate ligand in dinitrosyl iron complexes
作品名稱(其他語言)
著者 Hsieh, Chung-Hung; Brothers, Scott M.; Hall, Michael B.; Popescu, Codrina V.; Darensbourg, Marcetta Y.
作品所屬單位 淡江大學化學學系
出版者
會議名稱 245th ACS National Meeting & Exposition
會議地點 New Orleans, LA, United States
摘要 Ambidentate ligands such as thiocyanate (SCN-), cyanate (OCN-) and azide (N3 -) have played important roles in the development of bonding models relating to factors that control linkage isomerism in transition metal complexes. However, examples of DNICs, for which oxidn. states of iron are ambiguous, contg. these ambidentate ligands are rare. Two redox levels are prevalent for DNICs, represented in the Enemark-Feltham (E-F) notation as {Fe(NO)2}9 and {Fe(NO)2}10 for oxidized and reduced levels resp., eac...
關鍵字
語言 en
收錄於
會議性質 國際
校內研討會地點
研討會時間 20130407~20130411
通訊作者
國別 USA
公開徵稿 Y
出版型式 紙本
出處 245th ACS National Meeting & Exposition, INOR-96
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