Further mechanistic studies of carbon monoxide induced reductive elimination of disulfide in N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complexes (DNICs) | |
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學年 | 102 |
學期 | 2 |
發表日期 | 2014-03-16 |
作品名稱 | Further mechanistic studies of carbon monoxide induced reductive elimination of disulfide in N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complexes (DNICs) |
作品名稱(其他語言) | |
著者 | Drummond, Michael J.; Pulukkody, Randara; Kyran, Samuel J.; Hsieh, Chung Hung; Darensbourg, Donald J.; Darensbourg, Marcetta Y. |
作品所屬單位 | 淡江大學化學學系 |
出版者 | |
會議名稱 | 247th ACS National Meeting & Exposition |
會議地點 | Dallas, TX, United States |
摘要 | Dinitrosyliron complexes (DNICs) are biol. relevant mols. involved in nitric oxide (NO) transport and storage in biol. systems. Biol. DNICs are known to be products of iron-sulfur cluster degrdn. by excess NO, or derived from the chelatable iron pool (CIP) in cells; synthetic DNIC analogs have potential as NO storage and release agents with therapeutic benefit. The dinitrosyl iron unit is known to exist in two redox levels; its oxidized and reduced forms, {Fe(NO)2}9 and {Fe(NO)2}10 resp. (Enemark-Feltham notation) with redox potentials dependent o... |
關鍵字 | |
語言 | en |
收錄於 | |
會議性質 | 國際 |
校內研討會地點 | |
研討會時間 | 20140316~20140320 |
通訊作者 | |
國別 | USA |
公開徵稿 | Y |
出版型式 | 紙本 |
出處 | 247th ACS National Meeting & Exposition, CHED-774 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97590 ) |