Further mechanistic studies of carbon monoxide induced reductive elimination of disulfide in N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complexes (DNICs)
學年 102
學期 2
發表日期 2014-03-16
作品名稱 Further mechanistic studies of carbon monoxide induced reductive elimination of disulfide in N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complexes (DNICs)
作品名稱（其他語言）
著者 Drummond, Michael J.; Pulukkody, Randara; Kyran, Samuel J.; Hsieh, Chung Hung; Darensbourg, Donald J.; Darensbourg, Marcetta Y.
作品所屬單位 淡江大學化學學系
出版者
會議名稱 247th ACS National Meeting & Exposition
會議地點 Dallas, TX, United States
摘要 Dinitrosyliron complexes (DNICs) are biol. relevant mols. involved in nitric oxide (NO) transport and storage in biol. systems. Biol. DNICs are known to be products of iron-sulfur cluster degrdn. by excess NO, or derived from the chelatable iron pool (CIP) in cells; synthetic DNIC analogs have potential as NO storage and release agents with therapeutic benefit. The dinitrosyl iron unit is known to exist in two redox levels; its oxidized and reduced forms, {Fe(NO)2}9 and {Fe(NO)2}10 resp. (Enemark-Feltham notation) with redox potentials dependent o...
關鍵字
語言 en
收錄於
會議性質 國際
校內研討會地點
研討會時間 20140316~20140320
通訊作者
國別 USA
公開徵稿 Y
出版型式 紙本
出處 247th ACS National Meeting & Exposition, CHED-774
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