| 幾丁聚醣選擇性接枝聚異丙基丙烯醯胺以合成出共聚合體水膠 | |
|---|---|
| 學年 | 94 |
| 學期 | 2 |
| 發表日期 | 2006-05-27 |
| 作品名稱 | 幾丁聚醣選擇性接枝聚異丙基丙烯醯胺以合成出共聚合體水膠 |
| 作品名稱（其他語言） | Synthesis of Chitosan Copolymers Selectively Grafted withPoly(N-Isopropylacrylamide) |
| 著者 | 董崇民; 方裕榮; 陳怡雯 |
| 作品所屬單位 | 淡江大學化學工程學系 |
| 出版者 | |
| 會議名稱 | 2006台灣幾丁質幾丁聚醣研討會 |
| 會議地點 | 臺中, 臺灣 |
| 摘要 | In this study, poly(N-isopropylacrylamide)(PNIPAAm) was selectively grafted onto chitosan to form a copolymer hydrogel. To accomplish this goal, the amino group of chitosan (CS) was protected by reaction with phthalic anhydride, which also rendered the modified chitosan soluble in organic solvent. The N-phthaloyl chitosan was then reacted with glycidyl methacrylate (GMA) selectively through hydroxyl groups in glucopyranose rings, to provide vinyl functional groups for further graft copolymerization with NIPAAm monomer by free radical polymerization. The phthaloyl groups were removed under the reaction with hydrazine solution. Structures of the intermediates and final CS-g-PNIPAAm copolymer products were analyzed by Fourier transform infrared spectrometer and nuclear magnetic resonance. Several properties such as swelling behavior, thermal properties and cell compatibility of the formed chitosan-g-PNIPAAm copolymers were evaluated. |
| 關鍵字 | Chitosan;Poly(N-isopropylacrylamide);Glycidyl methacrylate;Graft copolymer |
| 語言 | en |
| 收錄於 | |
| 會議性質 | |
| 校內研討會地點 | |
| 研討會時間 | 20060527~20060527 |
| 通訊作者 | |
| 國別 | TWN |
| 公開徵稿 | Y |
| 出版型式 | 紙本 |
| 出處 | 2006台灣幾丁質幾丁聚醣研討會論文集，4頁 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/94985 ) |
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