Preparation and characterization of polymer/zirconia nanocomposite antistatic coatings on plastic substrates
學年 101
學期 1
出版（發表）日期 2013-01-01
作品名稱 Preparation and characterization of polymer/zirconia nanocomposite antistatic coatings on plastic substrates
作品名稱（其他語言）
著者 Chang, Chao-Ching; Hwang, Feng-His; Hsieh, Chin-Yuan; Chen, Ching-Chung; Cheng, Liao-Ping
單位 淡江大學化學工程與材料工程學系 淡江大學能源與光電材料研究中心
出版者 New York: Springer New York LLC
著錄名稱、卷期、頁數 Journal of Coatings Technology and Research 10(1), pp.73-78
摘要 Zirconia nanoparticles synthesized by the sol–gel method were surface modified by the coupling agent, 3-(trimethoxy silyl) propyl methacrylate (MSMA), containing C=C bonds. These particles were then UV-cured together with the hexa-functional monomer, dipentaethritol hexaacrylate (DPHA), to prepare transparent coatings that exhibited antistatic property on plastic substrates. FTIR and solid 29SiNMR were used to analyze the chemical bonds in the formed particles and coatings. Dynamic light scattering measurement of the modified ZrO2 sol indicated a relatively small particle size distribution, 1.5–20 nm, with a maximum intensity at ~5.5 nm. These particles dispersed uniformly in the organic host, poly(DPHA), as was manifested by the high resolution SEM images of the coatings. Antistatic performance of the coatings was examined based on the surface resistivity measurements. A resistivity of 7.74 × 108 Ω/□ suited to common antistatic applications could be attained for coatings containing 10% inorganic component. In addition, all of the prepared coatings were very hard with pencil hardness 7H–8H, and they attached perfectly to the PMMA substrate according to the peel test.
關鍵字 Zirconia; Antistatic; UV-curing; Acrylate resin; Hardness
語言 en
ISSN 1547-0091 1935-3804
期刊性質 國外
收錄於 SCI
產學合作
通訊作者
審稿制度 是
國別 USA
公開徵稿
出版型式 電子版 紙本
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