Synthesis, spectroscopic and magnetic properties of the charge-transfer complex Bifc.C60
學年 85
學期 2
出版（發表）日期 1997-02-01
作品名稱 Synthesis, spectroscopic and magnetic properties of the charge-transfer complex Bifc.C60
作品名稱（其他語言）
著者 Wang, Wen Jwu; Lay, Y. L.; Chang, Chen Shen; Chiu, Haw Shyi; Chuang, Kuo Shen; Wang, Bo Cheng
單位 淡江大學化學學系
出版者 Lausanne: Elsevier S.A.
著錄名稱、卷期、頁數 Synthetic Metals 86(1 -3 pt 3), pp.2293-2294
摘要 Charge-transfer complex of C60 with 1,1'-biferrocene(Bifc) was prepared. The charge-transfer property was investigated by infrared and uv/vis/nir spectroscopy. The charge-transfer process was studied in detail by electron paramagnetic resonance spectroscopy. A complex reaction behavior has been observed. Studies of variable temperature EPR in the solid state show g-value shift as well as with peak-width change. A relaxation with degradation process of this charge-transfer complex was proposed. Magnetic studies conducted by SQUID magnetometer show that the magnetic behavior of these charge-transfer complexes could be described as superposition of paramagnetic and ferromagnetic components. The coercive forces and residual magnetizations of these complexes measured at low temperature are discussed.
關鍵字 Charge transfer;Chemical reactions;Coercive force;Degradation;Electron spin resonance spectroscopy;Infrared spectroscopy;Magnetic properties;Magnetic variables measurement;Magnetization;Magnetometers;SQUIDs;Synthesis (chemical);Biferrocene;Charge transfer complex;Charge transfer property;G value shift;Peak width change;Ultraviolet visible near infrared spectroscopy;Organic conductors
語言 en
ISSN 0379-6779
期刊性質 國外
收錄於
產學合作
通訊作者
審稿制度
國別 SWZ
公開徵稿
出版型式 紙本
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