| 標題：PMR Spectroscopy Studies on Hydrogen Bonding of Iodoform with Several Proton Acceptors |
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| 學年 | 64 |
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| 學期 | 1 |
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| 出版（發表）日期 | 1975/12/01 |
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| 作品名稱 | PMR Spectroscopy Studies on Hydrogen Bonding of Iodoform with Several Proton Acceptors |
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| 作品名稱（其他語言） | |
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| 著者 | 陳敦禮; Chen, Tun-li; Chen, C. K. |
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| 單位 | 淡江大學化學學系 |
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| 出版者 | 臺北市：中國化學學會 |
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| 著錄名稱、卷期、頁數 | 中國化學會會誌=Journal of the Chinese Chemical Society 22(4)，頁279-284 |
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| 摘要 | The Benesi-Hildebrand method was used in NMR Spectroscopy to study the hydrogen bonding of iodoform with ten proton acceptors in cyclohexane at 25℃. The values of K's (M¯1) and Δc's (H2) of iodoform systems were determined as followings: N, N-dimethylacetamide, 0.73, 50.5; cyclohexylamine, 0.64, 40.6; cyclohexanone, 0.65, 38.9; cyclopentanone, 0.62, 41.5; 3-pentanone, 0.58, 36.0; acetone, 0.56, 35.0; ethylacetate, 0.51, 32.8; dioxane, 0.54, 31.3; tetrahydrofuran, 0.53, 28.8; diethylether, 0.36, 20.7. The experimental results were discussed. The H-bonding strength decreases in the order as: N, N-dimethylacetamide>cyclohexylamine≈ketone>ester>ether. |
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| 關鍵字 | |
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| 語言 | 英文 |
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| ISSN | 0009-4536 |
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| 期刊性質 | 國內 |
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| 收錄於 | SCI; |
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| 產學合作 | |
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| 通訊作者 | |
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| 審稿制度 | 否 |
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| 國別 | 中華民國 |
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| 公開徵稿 | |
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| 出版型式 | ,紙本 |
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| 相關連結 | |
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| SDGs | |
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