標題:Kinetic study of Bi1.8Pb0.4Ca2Sr2Cu3Oy superconductor in water |
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學年 | 82 |
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學期 | 1 |
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出版(發表)日期 | 1993/10/01 |
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作品名稱 | Kinetic study of Bi1.8Pb0.4Ca2Sr2Cu3Oy superconductor in water |
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作品名稱(其他語言) | |
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著者 | Wang, C. M.; Wei, T.P.; Kao, H.-C. I. |
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單位 | 淡江大學化學學系 |
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出版者 | Amsterdam: Elsevier BV * North-Holland |
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著錄名稱、卷期、頁數 | Physica C: Superconductivity 215(3-4), pp.391-394 |
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摘要 | The reaction of Bi1.8Pb0.4Ca2Sr2Cu3Oy powder in water was studied quantitatively. It was found that the [H3O+] ion would act as a catalyst in this reaction and the initial rate equation was R0 = -d[A]0/dt = k[A]0[H3O+]0.20, where [A] represented the surface area of the superconducting powder. The rate constant, k, obtained at 10, 25 and 40°C was 3.98, 8.8 and 19.6 × 10-4 mol min-1 cm-2 M0.8, respectively. The activation energy and pre-exponential factor calculated from the Arrhenius equation were respectively 39.1 kJ mol-1 and 6.4 × 103 mol min-1 cm-2 M0.8. |
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關鍵字 | |
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語言 | 英文 |
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ISSN | 0921-4534 |
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期刊性質 | 國外 |
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收錄於 | SCI |
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產學合作 | |
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通訊作者 | |
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審稿制度 | |
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國別 | 荷蘭 |
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公開徵稿 | |
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出版型式 | 紙本 |
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