Kinetic study of Bi1.8Pb0.4Ca2Sr2Cu3Oy superconductor in water
學年 82
學期 1
出版(發表)日期 1993-10-01
作品名稱 Kinetic study of Bi1.8Pb0.4Ca2Sr2Cu3Oy superconductor in water
作品名稱(其他語言)
著者 Wang, C. M.; Wei, T.P.; Kao, H.-C. I.
單位 淡江大學化學學系
出版者 Amsterdam: Elsevier BV * North-Holland
著錄名稱、卷期、頁數 Physica C: Superconductivity 215(3-4), pp.391-394
摘要 The reaction of Bi1.8Pb0.4Ca2Sr2Cu3Oy powder in water was studied quantitatively. It was found that the [H3O+] ion would act as a catalyst in this reaction and the initial rate equation was R0 = -d[A]0/dt = k[A]0[H3O+]0.20, where [A] represented the surface area of the superconducting powder. The rate constant, k, obtained at 10, 25 and 40°C was 3.98, 8.8 and 19.6 × 10-4 mol min-1 cm-2 M0.8, respectively. The activation energy and pre-exponential factor calculated from the Arrhenius equation were respectively 39.1 kJ mol-1 and 6.4 × 103 mol min-1 cm-2 M0.8.
關鍵字
語言 en
ISSN 0921-4534
期刊性質 國外
收錄於 SCI
產學合作
通訊作者
審稿制度
國別 NLD
公開徵稿
出版型式 紙本
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