| Photocatalytic abilities of gel-derived P-doped TiO2 | |
|---|---|
| 學年 | 95 |
| 學期 | 2 |
| 出版（發表）日期 | 2007-04-01 |
| 作品名稱 | Photocatalytic abilities of gel-derived P-doped TiO2 |
| 作品名稱（其他語言） | |
| 著者 | Yu, Hsuan-Fu |
| 單位 | 淡江大學化學工程與材料工程學系 |
| 出版者 | Kidlington: Pergamon |
| 著錄名稱、卷期、頁數 | Journal of Physics and Chemistry of Solids 68(4), pp.600-607 |
| 摘要 | P-doped TiO2 nanoparticles were synthesized through hydrolysis and condensation of Ti(OC2H5)4 with H3PO4 additions. Effects of [H3PO4]/[Ti(OC2H5)4] molar ratios on the anatase-to-rutile phase transformation, crystallite sizes, surface areas, and photocatalytic abilities of the gel-derived P-doped TiO2 were investigated. The P-doped TiO2 nanoparticles prepared by [H3PO4]/[Ti(OC2H5)4]=0.03 were composed of anatase monophase even at 900 oC and possessed very strong photocatalytic ability. Kinetic studies on the P-doped TiO2 to photocatalytically decompose methylene blue under irradiation of 365 nm UV light found that the P-doped TiO2 prepared by [H3PO4]/[Ti(OC2H5)4]=0.03 and calcined at 800 oC had the specific reaction rates, at 25 °C, kA,m=0.76 m3/(kg min) (based on the mass of P-doped TiO2) and kA,BET=46.2×10−6 m/min (based on the BET surface area of P-doped TiO2), which is superior to the performance of a commercial product, P25 (kA,m=0.22 m3/(kg min) and kA,BET=4.8×10−6 m/min). |
| 關鍵字 | A. Ceramics;A. Semiconductors;B. Chemical synthesis;C. X-ray diffraction;D. Phase transitions |
| 語言 | en |
| ISSN | 0022-3697 |
| 期刊性質 | 國外 |
| 收錄於 | SCI EI |
| 產學合作 | |
| 通訊作者 | Yu, Hsuan-Fu |
| 審稿制度 | |
| 國別 | GBR |
| 公開徵稿 | |
| 出版型式 | 紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/44185 ) |
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