教師資料查詢 | 類別: 期刊論文 | 教師: 董崇民 Don, Trong-ming (瀏覽個人網頁)

標題:Preparation and properties of chitosan/clay (nano)composites: a silanol quaternary ammonium intercalated clay
學年
學期
出版(發表)日期2012/02/01
作品名稱Preparation and properties of chitosan/clay (nano)composites: a silanol quaternary ammonium intercalated clay
作品名稱(其他語言)
著者Chiu, F.-C.; Lai, S.-M.; Hsieh, I.-C.; Don, T.-M.; Huang, C.-Y.
單位淡江大學化學工程與材料工程學系
出版者Dordrecht: Springer Netherlands
著錄名稱、卷期、頁數Journal of Polymer Research 19(2), 9781(11pages)
摘要Chitosan/clay (nano)composites were prepared by using a special quaternary ammonium intercalating agent coupled with a silanol group to facilitate the organic clay formation. Exfoliated clay in the chitosan matrix was attained at the higher intercalant dosages through X-ray diffraction (XRD) and transmission electron microscope (TEM) analyses. Optical transmittance for the (nano)composites increased slightly with increasing the amount of intercalants in the clays. In light of the hydrophobic component on the intercalant and the effective clay content, the interfacial interaction between chitosan and modified clay may not be strong enough to render higher mechanical properties, even though the partially exfoliated clays were achieved to provide high interfacial area for the dispersed phase and the matrix. An optimum Young’s modulus was thus found for (nano)composites using modified clay at a medium dosage of intercalant, which resulted from the balance of the dispersion status and interfacial interaction. This outcome indicated high dispersion of modified clay may not guarantee high mechanical properties of (nano)composites. The antimicrobial property of chitosan against Escherichia coli (E. coli) increased further with the addition of modified clays, in which the intercalant exhibiting the antimicrobial function. The modified clay at an optimum dosage of modifier to balance the mechanical properties and antimicrobial property was attained.
關鍵字Chitosan;Montmorillonite;(Nano)composites;Mechanical property ;Antimicrobial property
語言英文
ISSN1572-8935
期刊性質國外
收錄於SCI;
產學合作
通訊作者Lai, S.-M.
審稿制度
國別荷蘭
公開徵稿
出版型式,電子版,紙本
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