教師資料查詢 | 類別: 期刊論文 | 教師: 吳容銘 Wu Jung-ming (瀏覽個人網頁)

標題:Fitting TGA Data of Oil Sludge Pyrolysis and Oxidation by Applying a Model Free Approximation of the Arrhenius Parameters
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出版(發表)日期2006/06/01
作品名稱Fitting TGA Data of Oil Sludge Pyrolysis and Oxidation by Applying a Model Free Approximation of the Arrhenius Parameters
作品名稱(其他語言)
著者Wu, R. M.; D. J. Lee; C. Y. Chang; J. L. Shie
單位淡江大學化學工程與材料工程學系
出版者Amsterdam: Elsevier BV
著錄名稱、卷期、頁數Journal of Analytical and Applied Pyrolysis 76(1-2), pp.132-137
摘要Interpreting the thermal pyrolysis data from organic substances using thermogravimetric analysis (TGA) requires assuming certain formal kinetic models to be a priori for parametric fitting. The form of the assumed model limits the accuracy of stimulating the pyrolysis data. This work demonstrates the feasibility of modeling the pyrolyzed sample as a continuous mixture, in which an Arrhenius-type kinetics is applied with activation energy, pre-exponential factor, and reaction order as continuous functions of conversion. Such a data fitting scheme is not used to identify the actual chemical kinetics involved, but rather to describe the complex chemical kinetics in a unified, “model free” manner for engineering applications.
關鍵字Thermal pyrolysis; Continuous mixture; Oil sludge; Kinetics
語言英文
ISSN0165-2370
期刊性質國外
收錄於SCI;EI
產學合作
通訊作者
審稿制度
國別荷蘭
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