A new UV-curable PU resin obtained through a nonisocyanate process and used as a hydrophilic textile treatment
學年 100
學期 2
出版（發表）日期 2012-07-01
作品名稱 A new UV-curable PU resin obtained through a nonisocyanate process and used as a hydrophilic textile treatment
作品名稱（其他語言）
著者 Hwang, Jing-Zhong; Wang, Shih-Chieh; Chen, Po-Chen; Huang, Chi-Yuan; Yeh, Jen-Taut; Chen, Kan-Nan
單位 淡江大學化學學系 淡江大學化學工程與材料工程學系
出版者 Dordrecht: Springer Netherlands
著錄名稱、卷期、頁數 Journal of Polymer Research 19(8), 9900(10pages)
摘要 A new UV-curable hydrophilic PU resin was obtained through a green, nonisocyanate, three-reaction process: (1) a bis(cyclic carbonate) (BCC) compound is prepared by inserting carbon dioxide into an epoxy resin (DGEBA) at atmospheric pressure; (2) an amino-terminated hydrophilic PU (NH2-PU) oligomer is obtained through the ring-opening polymerization of BCC utilizing a difunctional amino hydrophilic (polyether) compound such as Jeffamine D-2000; (3) the UV-curable acrylate-PU (UV-PU) prepolymer is obtained as an adduct from the Michael addition of NH2-PU to a diacrylate-terminated compound, 3-acryloyloxy-2-hydroxypropyl methacrylate (AHM). A polyester (PET) textile was treated with this hydrophilic UV-PU prepolymer and then cured by irradiation with UV light. The UV-PU resin was found to crosslink and anchor to the textile fibers after UV irradiation, resulting in a long-lasting hydrophilic surface for the treated textile. The performance properties of the new PU resin on the treated textile were investigated.
關鍵字 Nonisocyanate process; Cyclic carbonate; Hydrophilic; PU; UV curing
語言 en
ISSN 1022-9760; 1572-8935
期刊性質 國外
收錄於 SCI
產學合作
通訊作者
審稿制度 是
國別 NLD
公開徵稿
出版型式 紙本
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