Field emission effects of nitrogenated carbon nanotubes on chlorination and oxidation
學年 97
學期 1
出版(發表)日期 2008-09-01
作品名稱 Field emission effects of nitrogenated carbon nanotubes on chlorination and oxidation
作品名稱(其他語言)
著者 Ray, S. C.; Palnitkar, U.; Pao, C. W.; Tsai, H. M.; Pong, W. F.; Lin, I-Nan; Papakonstantinou, P.; Ganguly, Abhijit; Chen, L. C.; Chen, K. H.
單位 淡江大學物理學系
出版者 College Park: American Institute of Physics
著錄名稱、卷期、頁數 Journal of Applied Physics 104(6), 063710(5pages)
摘要 With reference to our recent reports [ Appl. Phys. Lett. 90, 192107 (2007) ; Appl. Phys. Lett. 91, 202102 (2007) ] about the electronic structure of chlorine treated and oxygen-plasma treated nitrogenated carbon nanotubes (N-CNTs), here we studied the electron field emission effects on chlorination (N-CNT:Cl) and oxidation (N-CNT:O) of N-CNT. A high current density (J) of 15.0 mA/cm2 has been achieved on chlorination, whereas low J of 0.0052 mA/cm2 is observed on oxidation compared to J = 1.3 mA/cm2 for untreated N-CNT at an applied electric field EA of ∼ 1.9 V/μm. The turn-on electric field (ETO) was ∼ 0.875. The 1.25 V/μm was achieved for N-CNT:Cl and N-CNT:O, respectively, with respect to ETO = 1.0 V/μm for untreated one. These findings are due to the formation of different bonds with carbon and nitrogen in the N-CNT during the process of chlorine (oxygen)-plasma treatment by the charge transfer, or else that changes the density of free charge carriers and hence enhances (reduces) the field emission properties of N-CNTs:Cl (N-CNTs:O).
關鍵字
語言 en
ISSN 0021-8979; 1089-7550
期刊性質 國外
收錄於 EI SCI
產學合作
通訊作者 Ray, S. C.
審稿制度
國別 USA
公開徵稿
出版型式 紙本
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