| Pyridine-Catalyzed Double C–N Coupling Reaction of an Isocyanate with Two Benzynes | |
|---|---|
| 學年 | 100 |
| 學期 | 1 |
| 出版（發表）日期 | 2012-01-01 |
| 作品名稱 | Pyridine-Catalyzed Double C–N Coupling Reaction of an Isocyanate with Two Benzynes |
| 作品名稱（其他語言） | |
| 著者 | Lee, Yi-Hsien; Chen, Yen-Chung; Hsieh, Jen-Chieh |
| 單位 | 淡江大學化學學系 |
| 出版者 | Weinheim: Wiley - V C H Verlag GmbH & Co. KGaA |
| 著錄名稱、卷期、頁數 | European Journal of Organic Chemistry 2012(2), pp.247–250 |
| 摘要 | A pyridine-catalyzed double C–N bond cross-coupling reaction involving two benzynes with an isocyanate was carried out. The coupling reaction proceeded through a unique pathway involving the formation of an unstable carbamic acid intermediate and facile decarboxylation. Subsequent nucleophilic addition/protonation of in situ prepared amines with benzynes afforded variously substituted diaryl- and triarylamines in moderate to good yields with tolerance of a variety of functional groups. |
| 關鍵字 | Benzyne; Amines; Arylation; Cross-coupling; Nucleophilic addition |
| 語言 | en |
| ISSN | 1099-0690 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | Hsieh, Jen-Chieh |
| 審稿制度 | |
| 國別 | DEU |
| 公開徵稿 | |
| 出版型式 | 電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/74781 ) |
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