Electronic structure and bonding properties of Si-doped hydrogenated amorphous carbon film
學年 93
學期 1
出版(發表)日期 2004-11-01
作品名稱 Electronic structure and bonding properties of Si-doped hydrogenated amorphous carbon film
作品名稱(其他語言)
著者 王文竹
單位 淡江大學化學學系
出版者 College Park: American Institute of Physics
著錄名稱、卷期、頁數 Applied Physics Letters 85(18), pp.4022-4024
摘要 This work investigates the C K-edge x-ray absorption near-edge structure (XANES), valence-band photoelectron spectroscopy (PES), and Fourier transform infrared (FTIR) spectra of Si-doped hydrogenated amorphous carbon films. The C K-edge XANES and valence-band PES spectra indicate that the sp2/sp3 population ratio decreases as the amount of tetramethylsilane vapor precursor increases during deposition, which suggest that Si doping% enhances sp3 and reduces sp2-bonding configurations. FTIR spectra show the formation of a polymeric sp3 C–Hn structure and Si–Hn bonds, which causes the Young’s modulus and hardness of the films to decrease with the increase of the Si content.
關鍵字
語言 en
ISSN 0003-6951
期刊性質 國外
收錄於 SCI
產學合作
通訊作者
審稿制度
國別 USA
公開徵稿
出版型式 紙本
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