Introduction of Phosphorus Flame Retardant into Polyurethane via a Post-curing Reaction
學年 88
學期 1
出版(發表)日期 1999-10-01
作品名稱 Introduction of Phosphorus Flame Retardant into Polyurethane via a Post-curing Reaction
作品名稱(其他語言)
著者 陳幹男
單位 淡江大學化學學系
出版者
著錄名稱、卷期、頁數 Journal of Applied Polymer Science 74(10), pp.2499-2509
摘要 Anionic aqueous-based polyurethane (PU) dispersions were derived from a water dispersion process of carboxylic groups containing PU prepolymers together with a neutralization and a chain extension. These PU prepolymers were prepared from a conventional polyaddition of isophorone diisocyanate, polypropylene glycol-1000, and dimethylolpropanic acid. A covalently bonded phosphorus was introduced into PU by a phosporus-containing curing agent. A series of phosphorus and multi-aziridinyl groups containing curing agents were synthesized for this purpose. Each of them served in a dual-function capacity as a postcuring agent for the anionic aqueous-based PU system. The resulting postcured PU exhibited improvements in its mechanical, physical, and thermal properties; furthermore, postcured PU synergistic flame inhibition was also observed due to the presence of nitrogen and phosphorus content in the process.
關鍵字
語言 en_US
ISSN 1097-4628 0021-8995
期刊性質 國外
收錄於
產學合作
通訊作者
審稿制度
國別 USA
公開徵稿
出版型式 ,電子版,紙本
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