Diffusiophoresis of a Sphere along the Axis of a Cylindrical Pore
學年 98
學期 2
出版(發表)日期 2010-02-15
作品名稱 Diffusiophoresis of a Sphere along the Axis of a Cylindrical Pore
作品名稱(其他語言)
著者 Hsu, Jyh-Ping; Hsu, Wei-Lun; Ku, Ming-Hong; Chen, Zheng-Syun; Tseng, Shiojenn
單位 淡江大學數學學系
出版者 Maryland Heights: Academic Press
著錄名稱、卷期、頁數 Journal of Colloid and Interface Science 342(2), pp.598-606
摘要 The diffusiophoresis of a charged spherical particle along the axis of an uncharged cylindrical pore filled with an electrolyte solution is analyzed theoretically. The influence of chemiphoresis, which includes two types of double-layer polarization, and that of electrophoresis arising from the difference in the diffusivities of the ionic species on the diffusiophoretic behavior of the particle are discussed. We have underlined the important difference between two cases: the first is a possibility for a particle to migrate to the low concentration side at low surface potentials (∼25 mV) along the axis of a cylindrical pore, while the second is that this migration occurs at high surface potentials (∼150 mV) in the case of a sphere in a spherical cavity.
關鍵字 Diffusiophoresis; Boundary effect; Sphere in cylindrical pore; Double-layer polarization
語言 en
ISSN 0021-9797
期刊性質 國外
收錄於 SCI EI
產學合作
通訊作者
審稿制度
國別 USA
公開徵稿
出版型式 紙本
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