Boundary effect on electrophoresis in a Carreau fluid: Simulated biocolloids at an arbitrary position in a charged spherical cavity
學年 97
學期 2
出版(發表)日期 2009-02-01
作品名稱 Boundary effect on electrophoresis in a Carreau fluid: Simulated biocolloids at an arbitrary position in a charged spherical cavity
作品名稱(其他語言)
著者 Hsu, J. P.; Chen, C. Y.; Yeh, L. H.; Tseng, S.
單位 淡江大學數學學系
出版者 Amsterdam: Elsevier BV
著錄名稱、卷期、頁數 Colloids and Surfaces B: Biointerfaces 69(1), pp.8–14
摘要 The electrophoresis of a charge-regulated spherical particle, which mimics biocolloids and particles covered by an artificial membrane, at an arbitrary position in a spherical cavity filled with a shear-thinning Carreau fluid is modeled under the conditions of low surface potential and weak applied electric field. We examine simultaneously the influences of the presence of a boundary, the nature of the fluid, and the charged conditions on the boundary and the particle surface on the electrophoretic behavior of the particle. The mobility of the particle in a shear-thinning Carreau fluid is larger than that in the corresponding Newtonian fluid, and the difference between the two increases with increasing mobility. For the present case, the particle is negatively charged, and due to the presence of an electroosmotic flow, the electrophoretic behavior of the particle for the case where the boundary is positively charged is more complicated than that when it is uncharged or negatively charged. The factors key to the mobility of the particle include the position and the relative size of the particle, the thickness of double layer, the nature of the fluid, the density of the dissociable functional groups on the particle surface and the associated equilibrium constant, and the pH of the bulk phase.
關鍵字 Electrophoresis; Biocolloids; Boundary effect; Sphere in spherical cavity; Carreau fluid
語言 en
ISSN 0927-7765
期刊性質 國外
收錄於 EI SCI
產學合作
通訊作者 Hsu, J. P.
審稿制度
國別 NLD
公開徵稿
出版型式 紙本
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