Comparison of electronic structures of orthorhombic and hexagonal manganites studied by X-ray absorption spectroscopy | |
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學年 | 93 |
學期 | 2 |
出版(發表)日期 | 2005-06-01 |
作品名稱 | Comparison of electronic structures of orthorhombic and hexagonal manganites studied by X-ray absorption spectroscopy |
作品名稱(其他語言) | |
著者 | Asokan, A.; Dong, C. L.; Bao, C. W.; Tsai, H. M.; Chiou, J. W.;張經霖; Chang, C. L.; 彭維鋒; Pong, W. F.; Duran,P.; Moure, C.; Pena,O. |
單位 | 淡江大學物理學系 |
出版者 | Elsevier |
著錄名稱、卷期、頁數 | Solid State Communications 134(12), pp.821-826 |
摘要 | Electronic structures of orthorhombic perovskite-type manganites (OM) and hexagonal manganites (HM) are compared by using X-ray absorption near edge structure spectroscopy. This study reveals that the environments around Mn and O ions in both the systems are different. These are reflected primarily in the lifting of degeneracy of the Mn 3d orbitals. Interestingly, the unoccupied Mn 3dx2−y2 orbital in HM is strongly hybridized with O 2p states and appears to be responsible for both long range orderings: ferroelectric ordering at high temperatures and ferromagnetic ordering at low temperatures. |
關鍵字 | A. Manganites;C. XANES;D. Electronic structure;E. X-ray absorption spectroscopy |
語言 | en |
ISSN | 0038-1098 |
期刊性質 | 國內 |
收錄於 | |
產學合作 | |
通訊作者 | |
審稿制度 | 否 |
國別 | TWN |
公開徵稿 | |
出版型式 | ,電子版 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/27910 ) |