| Inclusion of triphenylmethane derivatives by crown and linear O-containing molecules: selective interactions and crystal structures | |
|---|---|
| 學年 | 97 |
| 學期 | 1 |
| 出版（發表）日期 | 2009-01-01 |
| 作品名稱 | Inclusion of triphenylmethane derivatives by crown and linear O-containing molecules: selective interactions and crystal structures |
| 作品名稱（其他語言） | |
| 著者 | Fonari, Marina S.; Simonov, Yurii A.; 王文竹; Wang, Wen-jwu; Tang, Shang-wei; Ganin, Eduard V. |
| 單位 | 淡江大學化學學系 |
| 出版者 | Cambridge: R S C Publications |
| 著錄名稱、卷期、頁數 | CrystEngComm 11, pp.94-101 |
| 摘要 | The sulfamide derivative of triphenylmethanol, 3-[hydroxy(diphenyl)methyl]benzenesulfonamide (H2NSO2Ph)Ph2COH was synthesized and, alongside with the parent triphenylmethanol and triphenylmethylamine, was investigated for selective interactions with crown ethers of different dimensionality (12-18-membered cycles). The molecule of 12-crown-4 (12C4) appeared to be the best candidate for Ph3COH, Ph3CNH2 and Ph3CNH3·NCS, while (H2NSO2Ph)Ph2COH forms the complex exclusively with 18-crown-6 (18C6). The triphenylammonia trifluoroacetate, Ph3CNH3·CF3COO, selectively forms the complex only with 2-methoxyethanol. The crystalline products of the compositions (Ph3COH)2·12C4, (Ph3CNH2)2·12C4, (Ph3CNH3·NCS)2·12C4, [(H2NSO2Ph)Ph2COH]2·18C6 and Ph3CNH3·CF3COO CH3OCH2CH2OH were obtained and studied by X-ray single crystal diffraction. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 1466-8033 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | |
| 國別 | GBR |
| 公開徵稿 | |
| 出版型式 | 紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/50711 ) |
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