Electrochemical dopping of tetramethylammonium ions into C60 film
學年 86
學期 1
出版(發表)日期 1998-01-01
作品名稱 Electrochemical dopping of tetramethylammonium ions into C60 film
作品名稱(其他語言)
著者 王文竹; Wang, Wen-jwu; Chiu, H. S.; Lin, S. S.; Chang, C. S.; Chuang, K. S.
單位 淡江大學化學學系
出版者 Marcel Dekker
著錄名稱、卷期、頁數 Fullerene science and technology 6, pp.681-688
摘要 The electrochemical properties of C60 films were studied by cyclic voltammetry and electrochemical quartz crystal microbalance technique in organic electrolyte solution. Tetramethylammonium perchlorate was used as a supporting electrolyte in acetonitrile solution. Thin films are prepared by solvent quickly evaporated method on a preheated glassy carbon electrode. The electrochemical response of C60 films is consistent with a reduction mechanism that is dominated by ion transport to form contact ion pair. In the proposed mechanism, swelling of the film with solvent and intercalation of cations into the film proceed parallelly. The stability of the film with respect to successive redox cycles was also interpreted.
關鍵字
語言 en
ISSN 1064-122X
期刊性質 國內
收錄於
產學合作
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審稿制度
國別 TWN
公開徵稿
出版型式 ,電子版
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