Effect of Pr and Ca substitution on the (La1-x-uPrxCau)(Ba1.5Sr0.5)Cu3Oy superconductors
學年 91
學期 2
出版(發表)日期 2003-05-01
作品名稱 Effect of Pr and Ca substitution on the (La1-x-uPrxCau)(Ba1.5Sr0.5)Cu3Oy superconductors
作品名稱(其他語言)
著者 Lin, C. H.; 高惠春; Kao, H. C. I.
單位 淡江大學化學學系
出版者 Springer
著錄名稱、卷期、頁數 Journal of low temperature physics 131(3-4), pp.719-724
摘要 In the fully oxygenated single phase (La1−x−uPrxCau)(Ba1.5Sr0.5)Cu3Oy (0≤x≤1.00, 0≤u≤0.20) system, if u=0, the z-coordinate of the Ba site, z(Ba), and dBa–bp (distance between the Ba site and the basal plane) are lowered by increasing the amount of Pr in the (La1−xPrx)(Ba1.5Sr0.5)Cu3Oy series. On the contrary, if u≠0, z(Ba) and dBa–bp are raised by increasing the amount of Ca ion in the (La1−x−uPrxCau)(Ba1.5Sr0.5)Cu3Oy (0≤x≤0.30, 0≤u≤0.20) series. Linear relationships are found between z(Ba), dBa–bp and the oxygen stoichiometry (y). Tc and psh (the hole concentration in CuO2 layers) increase with increasing the angle of Cu(2)-Ba-Cu(2). Relative positions of the Cu(2) and Ba sites are important in determining the Tc of these 123 compounds.
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語言 en_US
ISSN 0022-2291
期刊性質 國外
收錄於
產學合作
通訊作者
審稿制度
國別 USA
公開徵稿
出版型式 ,紙本
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